Us6217748b1 process for hydrodesulfurization of diesel. Hydrodesulfurization an overview sciencedirect topics. A process for hydrodesulfurization of a sulfurcontaining petroleum hydrocarbon diesel gas oil comprising. The catalytic process of hydrodesulfurization, also known as hydrotreating, is the chemical process widely used to remove sulfur compounds from refined petroleum products such as gasoline or petrol, jet fuel, diesel fuel, and fuel oils. Process for hydrodesulfurization of diesel gas oil. Diesel hydro desulphurisation process flow diagram youtube. Sulfur content in diesel fuel is reduced by hydrodesulfurization process. Hydrodesulfurization of fuel oil refining, hydrocarbons. Hydrodesulfurization hds in combination with carbon rejection technologies, such as coking and fluid catalytic cracking fcc, are the main technologies industrially employed for the desulfurization of heavy oil rana et al. Hydrodesulfurization reactivities of various sulfur. Hydrodesulfurization sulfur sulfur converted to hydrogen sulfide h2s added hydrogen breaks carbon. This catalytic process is designed for 32,000 bpd of light gas oil lgo.
Request pdf hydrodesulfurization of diesel in a slurry reactor the need for more complete removal of sulfur from fuels is due to the lower allowable sulfur content in gasoline and diesel. The use of sulfurfree diesel is a global trend fig. The hydrodesulfurization hds of gasoil is one of the key processes in refineries that enables them to meet the product properties as demanded by the market 1,2. Mathematical modelling of diesel fuel hydrodesulfurization kinetics krivtcova n. Rem, voor een commissie aangewezen door het college voor promoties in het openbaar te verdedigen op dinsdag 4 april 2000. Hydrodesulfurization definition of hydrodesulfurization. A rigorous kinetic model of hydrodesulfurization hds of complex mixtures such as light cycle oil lco or diesel has been developed. Deep desulfurization of hydrodesulfurizationtreated. A threephase model of a trickedbed reactor was considered. Ultradeep hydrodesulfurization and adsorptive desulfurization of diesel fuel on metalrich nickel phosphides. The analysis is based on the computation of reactive and nonreactive residue curve maps for elimination of dibenzothiophene.
This process is used to upgrade the octane rating of. Hydrodesulfurization hds or hydrotreating is a catalytic chemical process widely used to remove sulfur compounds from. Hydrodesulfurization hds is a catalytic chemical process widely used to remove sulfur s from natural gas and from refined petroleum products, such as gasoline or petrol, jet fuel, kerosene, diesel fuel, and fuel oils. Multiobjective optimization of a hydrodesulfurization process. Different new catalysts have been reported in literature as highly active for the elimination of refractory s. Diesel hydrotreating process hydroprocessing for clean. Design parameters for a hydro desulfurization hds unit for. Bidholi via prem nagar, dehradun 248007, india email address. An overview of hydrodesulfurization and hydrodenitrogenation. The hdt process, especially deep hydrodesulfurization hds of diesel. In this work, a hydrotreatment unit fed with multiple diesel streams was optimized using a phenomenological mathematical model. Hydrodesulfurization hydrodesulfurization hds or hydrotreating is a catalytic chemical process widely used to remove sulfur compounds from refined petroleum products such as gasoline or petrol, jet fuel, diesel fuel, and fuel oils. Catalytic hydrodesulfurization is widely used in petroleum refineries to reduce sulfur. Due to incentives and regulations, 10 ppm sulfur diesel fuel has been commercially available in sweden for several years.
This dichotomy is exploited to develop an ultradeep hydrodesulfurization stacked. Depending on the type of catalyst and operational conditions, there may be desulfurization, denitrification, saturation of fine oils, and cracking reactions. Diesel hydrodesulfurization dhds hydrotreating dhdt technology background in view of growing importance of hydroprocessing, and to achieve. Moreover, by a deep hydrodesulfurization of sulfurcontaining diesel gas oil feedstock with a specific catalyst in specific proportion as well under specific hydrodesulfurization conditions, a light oil product with sulfur content of 0. Hydrodesulfurization of fuel oil posted in refining, hydrocarbons, oil, and gas. The distillation with side reactor has been proposed to remove sulfur compounds of diesel. The design and optimization of a hydrodesulfurization process involve the selection of the con. In this study, the hydrodesulfurization process for the production of ultralow sulfur diesel was simulated using the aspen hysys hydroprocessing bed module. The hds activity was measured with straightrun light gas oil feedstocks under actual hydrotreating conditions.
Jul 31, 2019 diesel hydrodesulfurization dhds employed in light gas oil production has been widely applied to remove various impurities such as sulfur, nitrogen, and metalorganic compounds. Isao mochida, kinya sakanishi, xiaoliang ma, shinichi nagao, takaaki. Topsoe offers hydrotreating catalysts and technologies for all crude oil fractions, enabling refineries to meet product specifications at a. Deep hydrodesulfurization hds of diesel fuel has attracted much attention in recent years due to environmental requirements demanding significant improvement in s elimination. In contrast, hydrogenolysis sites are more resistant to organonitrogen inhibition but are less active for desulfurizing refractory sulfur species. There is considerable interest in the use of monomeric and polymeric compounds made from heterocyclic sulfur. Conventional hydrodesulfurization hds is costly and works poorly at these low concentrations of sulfur. In refineries bohler solutions are used in distillation towers, heaters, coke drums, fractionators, hydrocracking reactors, hydrotreating reactors, hydrodesulphurisation reactors, heat exchangers, fcc units, evaporators, storage tanks and reforming units. A theory of ultradeep hydrodesulfurization of diesel in.
The total sulfur content of the diesel oil was reduced 86%. Hydrodesulfurization via heat exchanger network synthesis. Distillate hydrotreating hydrotreating processes aim at the removal of impurities such as sulfur and nitrogen from distillate fuelsnaphtha, kerosene, and diesel by treating the feed with hydrogen at elevated temperature. Hydrodesulfurization definition is the process of chemically removing sulfur from raw petroleum products such as crude oil or natural gas in order to make them more efficient and reduce combustion byproducts. Introduction hydrodesulphurization hds is a catalytic chemical process widely used to remove sulfur s from natural gas and from refined petroleum products such as gasoline or petrol, jet fuel, kerosene, diesel fuel, and fuel oils.
Diesel hydrodesulfurization dhds hydrotreating dhdt. Hydrodesulfurization via heat exchanger network synthesis for. Hydrodesulphurisation article about hydrodesulphurisation. Design parameters for a hydro desulfurization hds unit. This process is used to upgrade the octane rating of the naphtha streams. The optimization of the process was performed with the interior point method considering the hydrodesulfurization reaction of diesel.
The desulfurization product of benzonaphthothiophene was identified as. Different new catalysts have been reported in literature as highly active for the elimination of refractory scontaining aromatic compounds. An example process flow diagram is shown with material and energy balance for plant capacity 1mmtpa. Moreover, nitrogen compounds act certainly as inhibitors at hydrotreating and cracking process 12. Although these technologies are quite capable of desulfurizing heavy oil, their carbon footprints are substantial. Getting the greatest value out of crude oil and effectively processing all the fractions from very light gas and naphtha to residue can be challenging. The typical physicochemical properties of the catalyst samples were characterized by means of n2 adsorption, uv.
Comophyal 2 o 3 catalyst had three times higher hds activity compared with the conventional comopal 2 o 3 catalyst. Several types of sulfur compounds are present in diesel fuels. The entire work was performed in a hydrodesulphurization hds pilot plant unit located in chemical process engineering research institute cperi. Model and simulation of a hydrotreatment reactor for. Hydrodesulfurization reactions are favored by a reduction in vvh. The hds process should produce diesel with the target sulfur levels while meeting important product properties such as density, cetane index, and coldflow properties. Request pdf hydrodesulfurization of diesel in a slurry reactor the need for more complete removal of sulfur from fuels is due to the lower. Multiobjective optimization of a hydrodesulfurization. Hydrodesulfurization and hydrodenitrogenation of diesel distillate from fushun shale oil 127 the heteroatomic compounds in shale oil may cause serious problems producing pollutants and lowering stability in storage.
Model and simulation of a hydrotreatment reactor for diesel. An experimental setup was constructed to investigate the hydrotreatment of complex mixtures. Resting cells could desulfurize diesel oil total sulfur, 535 ppm after hydrodesulfurization. Pdf in order to meet environmental norms, indian fuel policy aims at producing ultra low sulphur diesel ulsd in near future. Formation of free sulfur in hydrodesulfurized gas oilprecautions for pilot test of ultra deep hydrodesulfurization catalysts. Hydrodesulfurization hds or hydrotreater is a catalytic chemical process widely used to remove sulfur compounds from refined petroleum products such as gasoline or petrol, jet fuel, kerosene, diesel oil, and fuel oils.
The entire work was performed in a hydrodesulphurization hds pilot plant unit. Hydrodesulfurization definition of hydrodesulfurization by. Mathematical modelling of diesel fuel hydrodesulfurization. Resting cells could desulfurize diesel oil total organic sulfur, 259 ppm after hydrodesulfurization. The mathematical model of hydrotreating process is developed, the constant values for the reaction rate of hydrodesulfurization of the specified components are. It was found that the solvent concentration is very important in determining the. Mar 27, 2018 sulfur content in diesel fuel is reduced by hydrodesulfurization process. Amine gas treater, claus unit, and tail gas treatment for converting hydrogen sulphide gas from the hydrotreaters into endproduct elemental sulphur. Sep 16, 2017 in contrast, hydrogenolysis sites are more resistant to organonitrogen inhibition but are less active for desulfurizing refractory sulfur species.
Hyal 2 o 3supported como catalysts were prepared with citric acid and phosphorus for the hydrodesulfurization of diesel fractions. In this paper, the results of preliminary investigation into catalytic hydrotreating of diesel fraction 200360 c of fushun shale oil are presented. Hydrodesulfurization definition of hydrodesulfurization by the free dictionary. Model and simulation of a hydrotreatment reactor 1249 in order to decrease costs in process, it was design a hydrogen separation step through a fast cooling with a flash separator for the reactor outlet stream. Part of this hydrogen was recirculated to the process, so that reduce greatly the quantity of makeup. But although the hydrodesulfurization process tends to improve diesel quality by raising its cetane number, it decreases gasoline quality by lowering its octane number song and ma, 2003.
Hydrodesulfurization of diesel in a slurry reactor request pdf. The diesel hydrodearomatization hda and hydrodesulfurization hds activities of the catalysts were evaluated using a microreactor system. Development of highlyactive hydrodesulfurization catalyst. Us6217748b1 process for hydrodesulfurization of diesel gas. Mar 10, 2020 hydrodesulfurization, also known as hds, is a process in which sulfur is removed from crude oil, and oilderived feedstock for the petrochemical industry, by combining it with hydrogen to form hydrogen sulfide h 2 s. Distillate hydrotreating hydrotreating processes aim at the removal of impurities such as sulfur and nitrogen from distillate fuelsnaphtha, kerosene, and dieselby treating the feed with hydrogen at elevated temperature and pressure in the presence of a catalyst. Catalytic performance of nimos supported on zrsba15 for.
Hydrodesulfurization reactivities of various sulfur compounds in. Hydrodesulfurization encyclopedia article citizendium. The purpose of removing the sulfur, and creating products such as ultralowsulfur diesel, is to reduce the sulfur dioxide so. The present work investigates the hydrotreating process of a diesel in order to achieve lower sulphur and aromatics content. The hydrodesulfurization process is based on the addition of hydrogen to the petroleum fractions at elevated pressures and temperature in catalytic beds. The hydrodesulfurization of lco on a commercial comoal2o3 imp catalyst was. Hydrodesulfurization synonyms, hydrodesulfurization pronunciation, hydrodesulfurization translation, english dictionary definition of hydrodesulfurization.
Crude oil is thought to have formed over millions of years from layers of dead plankton on the seabed. An overview of new approaches to deep desulfurization for ultra. Other articles where hydrodesulfurization is discussed. Diesel hydrotreating dht or catalytic hydrogen treating is mainly to reduce undesirable species from straight. Gc flame ionization detection and gc atomic emission detection analyses were used to qualitatively evaluate the effect of mycobacterium sp. Mathematical modeling of diesel fuel hydrotreating iopscience. The sulfur content of diesel oil was reduced by 94. Hydrodesulfurization, also known as hds, is a process in which sulfur is removed from crude oil, and oilderived feedstock for the petrochemical industry, by combining it with hydrogen to form hydrogen sulfide h 2 s. Insight into a onestep calcination and reduction strategy during. Performance testing of hydrodesulfurization catalysts. Molybdenumcontaining hydrodesulfurization catalysts are used in the removal of the undesirable sulfur compounds from petroleum, giving hydrocarbons and hydrogen sulfide as the final products. The issues of gasoline and diesel deep desulfurization are becoming more serious because. There is considerable interest in the use of monomeric and polymeric compounds made from heterocyclic sulfur compoundssuch as thiophene.
Also, without their hydrodesulfurization units, their endproduct jet fuels, diesel fuels and heating fuels would not meet the various worldwide governmental regulations limiting the amount of sulfur in those refinery endproducts. Part of this hydrogen was recirculated to the process. This hydrodesulfurization unit is used to desulfurize desulphurize light gas oil lgo and kerosene to give a low sulfur product used for blending to give ultra low sulfur diesel ulsd. Hydrodesulfurization catalysis and mechanism of supported. Catalytic performance of nimos supported on zrsba15 for hydrodesulfurization of diesel. Diesel fuel desulfurization research project database. Diesel hydrodesulfurization dhds employed in light gas oil production has been widely applied to remove various impurities such as sulfur, nitrogen, and metalorganic compounds. A rigorous kinetic model of hydrodesulfurization hds of complex mixtures such. A thermodynamic analysis for the deep hydrodesulfurization of diesel through reactive distillation has been performed. Used 32,000 bpd hydrodesulfurization hds units built in 1990. Pdf hydrodesulfurization of diesel for molten carbonate. The hydrodesulfurization hds of a diesel oil was carried out in a batch autoclave reactor over the temperature range 280420 c for 090 min under a total pressure of 2.
A catalytic process in which the petroleum feedstock is reacted with hydrogen to reduce the sulfur content in the oil explanation of hydrodesulphurisation hydrodesulphurisation article about hydrodesulphurisation by the free dictionary. Hydrodesulfurization of diesel in a slurry reactor. The desulfurization methods including variations thereon that are discussed include hydrodesulfurization, extractive desulfurization, oxidative desulfurization, biodesulfurization and desulfurization through alkylation. Hydrodesulfurization of diesel in a slurry reactor article in chemical engineering science 651. Here r represents an alkyl group, such as methyl ch 3, or ethyl c 2 h 5. Desulfurization of fuels is commonly achieved by catalytic hydrodesulfurization hds, in which the organic sulfur species are converted to h 2 s and the corresponding hydrocarbon, as in the following reaction.
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